Fe and Mo valences in Sr2FeMoO6

M. S. Moreno; J. E. Gayone; M. Abbate; A. Caneiro; D. Niebieskikwiat; R. D. Sánchez; A. De Siervo; R. Landers; G. Zampieri

doi:10.1016/S0038-1098(01)00367-2

Fe and Mo valences in Sr₂FeMoO₆

M. S. Moreno
, J. E. Gayone
, M. Abbate
, A. Caneiro
, D. Niebieskikwiat
, R. D. Sánchez
, A. De Siervo
, R. Landers
, G. Zampieri^*

^*Corresponding author for this work

Universidad Nacional de Cuyo
Federal University of Parana
Universidade Estadual de Campinas

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The valences of Fe and Mo in Sr₂FeMoO₆ are investigated by means of X-ray absorption and photoemission spectroscopies. We find that the d occupations are similar to those of Fe in Fe₂O₃ and Mo in MoO₃. Considering the covalency, however, we argue that the ground state is closer to a Fe⁺³(3d⁵)-Mo⁺⁵(4d¹) configuration than to a Fe⁺²(3d⁶)-Mo⁺⁶(4d⁰) configuration.

Original language	English
Pages (from-to)	161-164
Number of pages	4
Journal	Solid State Communications
Volume	120
Issue number	4
DOIs	https://doi.org/10.1016/S0038-1098(01)00367-2
State	Published - 1 Oct 2001
Externally published	Yes

Keywords

A. magnetically ordered materials
E. photoelectron spectroscopies

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10.1016/S0038-1098(01)00367-2

Cite this

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title = "Fe and Mo valences in Sr2FeMoO6",

abstract = "The valences of Fe and Mo in Sr2FeMoO6 are investigated by means of X-ray absorption and photoemission spectroscopies. We find that the d occupations are similar to those of Fe in Fe2O3 and Mo in MoO3. Considering the covalency, however, we argue that the ground state is closer to a Fe+3(3d5)-Mo+5(4d1) configuration than to a Fe+2(3d6)-Mo+6(4d0) configuration.",

keywords = "A. magnetically ordered materials, E. photoelectron spectroscopies",

author = "Moreno, \{M. S.\} and Gayone, \{J. E.\} and M. Abbate and A. Caneiro and D. Niebieskikwiat and S{\'a}nchez, \{R. D.\} and \{De Siervo\}, A. and R. Landers and G. Zampieri",

note = "Funding Information: Financial support by CONICET, Fundaci{\'o}n Antorchas, and ANPCyT of Argentina, and by LNLS of Brazil is gratefully acknowledged.",

year = "2001",

month = oct,

day = "1",

doi = "10.1016/S0038-1098(01)00367-2",

language = "Ingl{\'e}s",

volume = "120",

pages = "161--164",

journal = "Solid State Communications",

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publisher = "Elsevier Ltd",

number = "4",

}

TY - JOUR

T1 - Fe and Mo valences in Sr2FeMoO6

AU - Moreno, M. S.

AU - Gayone, J. E.

AU - Abbate, M.

AU - Caneiro, A.

AU - Niebieskikwiat, D.

AU - Sánchez, R. D.

AU - De Siervo, A.

AU - Landers, R.

AU - Zampieri, G.

N1 - Funding Information: Financial support by CONICET, Fundación Antorchas, and ANPCyT of Argentina, and by LNLS of Brazil is gratefully acknowledged.

PY - 2001/10/1

Y1 - 2001/10/1

N2 - The valences of Fe and Mo in Sr2FeMoO6 are investigated by means of X-ray absorption and photoemission spectroscopies. We find that the d occupations are similar to those of Fe in Fe2O3 and Mo in MoO3. Considering the covalency, however, we argue that the ground state is closer to a Fe+3(3d5)-Mo+5(4d1) configuration than to a Fe+2(3d6)-Mo+6(4d0) configuration.

AB - The valences of Fe and Mo in Sr2FeMoO6 are investigated by means of X-ray absorption and photoemission spectroscopies. We find that the d occupations are similar to those of Fe in Fe2O3 and Mo in MoO3. Considering the covalency, however, we argue that the ground state is closer to a Fe+3(3d5)-Mo+5(4d1) configuration than to a Fe+2(3d6)-Mo+6(4d0) configuration.

KW - A. magnetically ordered materials

KW - E. photoelectron spectroscopies

UR - https://www.scopus.com/pages/publications/0035476222

U2 - 10.1016/S0038-1098(01)00367-2

DO - 10.1016/S0038-1098(01)00367-2

M3 - Artículo

AN - SCOPUS:0035476222

SN - 0038-1098

VL - 120

SP - 161

EP - 164

JO - Solid State Communications

JF - Solid State Communications

IS - 4

ER -

Fe and Mo valences in Sr₂FeMoO₆

Abstract

Keywords

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