Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]

Thomas Cadenbach; Christian Gemel; Roland A. Fischer

doi:10.1002/anie.200803449

Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄]

Thomas Cadenbach, Christian Gemel, Roland A. Fischer

Ruhr-Universität Bochum

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Zinc in the middle: The reaction of [Mo-(GaCp*)₂(CO) ₄] and Zn(CH₃)₂ results in the cluster [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

Original language	English
Pages (from-to)	9146-9149
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	47
DOIs	https://doi.org/10.1002/anie.200803449
State	Published - 10 Nov 2008
Externally published	Yes

Keywords

Cluster compounds
Coordination chemistry
Gallium
Molybdenum
Zinc

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title = "Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]",

abstract = "Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).",

keywords = "Cluster compounds, Coordination chemistry, Gallium, Molybdenum, Zinc",

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T2 - Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]

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AU - Gemel, Christian

AU - Fischer, Roland A.

PY - 2008/11/10

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N2 - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

AB - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

KW - Cluster compounds

KW - Coordination chemistry

KW - Gallium

KW - Molybdenum

KW - Zinc

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ER -

Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄]

Abstract

Keywords

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