Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex Cp*Ir(μ-C6H4N-NC6H4)IrCp*

Cesar H. Zambrano; Paul R. Sharp; Charles L. Barnes

doi:10.1021/om00008a001

Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex CpIr(μ-C₆H₄N-NC₆H₄)IrCp

Cesar H. Zambrano
, Paul R. Sharp^*
, Charles L. Barnes

^*Corresponding author for this work

University of Missouri

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The hydrazido-bridged iridium complex (1; Cp* = C₅Me₅) reacts with H₂under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl₃Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br₂.

Original language	English
Pages (from-to)	3607-3610
Number of pages	4
Journal	Organometallics
Volume	14
Issue number	8
DOIs	https://doi.org/10.1021/om00008a001
State	Published - Aug 1995
Externally published	Yes

Access to Document

10.1021/om00008a001

Cite this

@article{1a3ae0428747445fba0c593b0fd82297,

title = "Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex Cp*Ir(μ-C6H4N-NC6H4)IrCp*",

abstract = "The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.",

author = "Zambrano, \{Cesar H.\} and Sharp, \{Paul R.\} and Barnes, \{Charles L.\}",

year = "1995",

month = aug,

doi = "10.1021/om00008a001",

language = "Ingl{\'e}s",

volume = "14",

pages = "3607--3610",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex Cp*Ir(μ-C6H4N-NC6H4)IrCp*

AU - Zambrano, Cesar H.

AU - Sharp, Paul R.

AU - Barnes, Charles L.

PY - 1995/8

Y1 - 1995/8

N2 - The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.

AB - The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.

UR - https://www.scopus.com/pages/publications/0029352838

U2 - 10.1021/om00008a001

DO - 10.1021/om00008a001

M3 - Artículo

AN - SCOPUS:0029352838

SN - 0276-7333

VL - 14

SP - 3607

EP - 3610

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex CpIr(μ-C₆H₄N-NC₆H₄)IrCp

Abstract

Access to Document

Other files and links

Fingerprint

Cite this