The reaction of RhCp*(CH3)2(L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon-carbon bond activation reaction

Thomas Cadenbach; Christian Gemel; Rochus Schmid; Stefan Block; Roland A. Fischer

doi:10.1039/b410077h

The reaction of RhCp(CH₃)₂(L) (L = pyridine, dmso) with GaCp and AlCp*: A new type of carbon-carbon bond activation reaction

Thomas Cadenbach
, Christian Gemel
, Rochus Schmid
, Stefan Block
, Roland A. Fischer^*

^*Corresponding author for this work

Ruhr-Universität Bochum

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Reaction of RhCp*(L)(CH₃)₂ (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe₄GaMe₃)]. [Cp*Rh(CH₃)₂(GaCp*)] could be isolated and identified as an intermediate in this reaction.

Original language	English
Pages (from-to)	3171-3172
Number of pages	2
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b410077h
State	Published - 21 Oct 2004
Externally published	Yes

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title = "The reaction of RhCp*(CH3)2(L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon-carbon bond activation reaction",

abstract = "Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.",

author = "Thomas Cadenbach and Christian Gemel and Rochus Schmid and Stefan Block and Fischer, \{Roland A.\}",

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T2 - A new type of carbon-carbon bond activation reaction

AU - Cadenbach, Thomas

AU - Gemel, Christian

AU - Schmid, Rochus

AU - Block, Stefan

AU - Fischer, Roland A.

PY - 2004/10/21

Y1 - 2004/10/21

N2 - Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

AB - Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

UR - https://www.scopus.com/pages/publications/9244250324

U2 - 10.1039/b410077h

DO - 10.1039/b410077h

M3 - Artículo

AN - SCOPUS:9244250324

SN - 1477-9226

SP - 3171

EP - 3172

JO - Dalton Transactions

JF - Dalton Transactions

IS - 20

ER -

The reaction of RhCp(CH₃)₂(L) (L = pyridine, dmso) with GaCp and AlCp*: A new type of carbon-carbon bond activation reaction

Abstract

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