Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst; Thomas Cadenbach; Daniel Betz; Colin Finn; Jason B. Love

doi:10.1039/c4dt03592e

Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst
, Thomas Cadenbach
, Daniel Betz
, Colin Finn
, Jason B. Love^*

^*Corresponding author for this work

EaStCHEM School of Chemistry, University of Edinburgh

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

Original language	English
Pages (from-to)	2066-2070
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	5
DOIs	https://doi.org/10.1039/c4dt03592e
State	Published - 7 Feb 2015
Externally published	Yes

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10.1039/c4dt03592e

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title = "Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes",

abstract = "Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.",

author = "Pankhurst, \{James R.\} and Thomas Cadenbach and Daniel Betz and Colin Finn and Love, \{Jason B.\}",

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doi = "10.1039/c4dt03592e",

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T2 - Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

AU - Pankhurst, James R.

AU - Cadenbach, Thomas

AU - Betz, Daniel

AU - Finn, Colin

AU - Love, Jason B.

PY - 2015/2/7

Y1 - 2015/2/7

N2 - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

AB - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

UR - https://www.scopus.com/pages/publications/84921517030

U2 - 10.1039/c4dt03592e

DO - 10.1039/c4dt03592e

M3 - Artículo

AN - SCOPUS:84921517030

SN - 1477-9226

VL - 44

SP - 2066

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

Abstract

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