Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]

Thomas Cadenbach; Christian Gemel; Roland A. Fischer

doi:10.1002/anie.200803449

Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄]

Thomas Cadenbach, Christian Gemel, Roland A. Fischer

Ruhr-Universität Bochum

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

35 Citas (Scopus)

Resumen

Zinc in the middle: The reaction of [Mo-(GaCp*)₂(CO) ₄] and Zn(CH₃)₂ results in the cluster [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

Idioma original	Inglés
Páginas (desde-hasta)	9146-9149
Número de páginas	4
Publicación	Angewandte Chemie - International Edition
Volumen	47
N.º	47
DOI	https://doi.org/10.1002/anie.200803449
Estado	Publicada - 10 nov. 2008
Publicado de forma externa	Sí

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title = "Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]",

abstract = "Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).",

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AU - Fischer, Roland A.

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N2 - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

AB - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

KW - Cluster compounds

KW - Coordination chemistry

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KW - Molybdenum

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