Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]

Thomas Cadenbach; Christian Gemel; Roland A. Fischer

doi:10.1002/anie.200803449

Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄]

Thomas Cadenbach^*
, Christian Gemel
, Roland A. Fischer

^*Autor correspondiente de este trabajo

Ruhr-Universität Bochum

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

35 Citas (Scopus)

Resumen

Zinc in the middle: The reaction of [Mo-(GaCp*)₂(CO) ₄] and Zn(CH₃)₂ results in the cluster [{Mo(CO)₄}₄(Zn)₆(μ-ZnCp*) ₄] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

Idioma original	Inglés
Páginas (desde-hasta)	9146-9149
Número de páginas	4
Publicación	Angewandte Chemie - International Edition
Volumen	47
N.º	47
DOI	https://doi.org/10.1002/anie.200803449
Estado	Publicada - 10 nov. 2008
Publicado de forma externa	Sí

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title = "Molecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [\{Mo(CO)4\}4(Zn)6(μ-ZnCp*) 4]",

abstract = "Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [\{Mo(CO)4\}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).",

keywords = "Cluster compounds, Coordination chemistry, Gallium, Molybdenum, Zinc",

author = "Thomas Cadenbach and Christian Gemel and Fischer, \{Roland A.\}",

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T2 - Synthesis and structure of [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4]

AU - Cadenbach, Thomas

AU - Gemel, Christian

AU - Fischer, Roland A.

PY - 2008/11/10

Y1 - 2008/11/10

N2 - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

AB - Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)4}4(Zn)6(μ-ZnCp*) 4] (see picture), the first metalloid cluster with naked zinc atoms as cluster elements. This complex indeed represents a molecular cut-out of a Mo/Zn alloy, which is not only substantiated by similar interatomic distances but by direct comparison of coordination environments of the metal atoms. (Figure Presented).

KW - Cluster compounds

KW - Coordination chemistry

KW - Gallium

KW - Molybdenum

KW - Zinc

UR - https://www.scopus.com/pages/publications/56249125972

U2 - 10.1002/anie.200803449

DO - 10.1002/anie.200803449

M3 - Artículo

AN - SCOPUS:56249125972

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VL - 47

SP - 9146

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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