Substituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru2(Ga)(GaCp*) 7(H)3]

Thomas Cadenbach; Christian Gemel; Rochus Schmid; Markus Halbherr; Kirill Yusenko; Mirza Cokoja; Roland A. Fischer

doi:10.1002/anie.200805605

Substituent-free gallium by hydrogenolysis of coordinated gaCp: Synthesis and structure of highly fluxional [Ru₂(Ga)(GaCp) ₇(H)₃]

Thomas Cadenbach, Christian Gemel, Rochus Schmid, Markus Halbherr, Kirill Yusenko, Mirza Cokoja, Roland A. Fischer

Ruhr-Universität Bochum

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42 Citas (Scopus)

Resumen

All change: Complete ligand exchange through the hydrogenation of [Ru(η⁴-cod)(η₆-cot)] in the presence of GaCp* under mild conditions leads to the title complex featuring a "naked" gallium atom bridging two ruthenium centers (see structure: C white, Ga blue, Ru red). This cluster can be considered as a trapped intermediate on the way to mixed-metal nanoparticles; cot=1,3,5- cyclooctatriene; cod=1,5-cyclooctadiene, Cp*=C₅Me₅.

Idioma original	Inglés
Páginas (desde-hasta)	3872-3876
Número de páginas	5
Publicación	Angewandte Chemie - International Edition
Volumen	48
N.º	21
DOI	https://doi.org/10.1002/anie.200805605
Estado	Publicada - 11 may. 2009
Publicado de forma externa	Sí

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title = "Substituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru2(Ga)(GaCp*) 7(H)3]",

abstract = "All change: Complete ligand exchange through the hydrogenation of [Ru(η4-cod)(η6-cot)] in the presence of GaCp* under mild conditions leads to the title complex featuring a {"}naked{"} gallium atom bridging two ruthenium centers (see structure: C white, Ga blue, Ru red). This cluster can be considered as a trapped intermediate on the way to mixed-metal nanoparticles; cot=1,3,5- cyclooctatriene; cod=1,5-cyclooctadiene, Cp*=C5Me5.",

keywords = "Cluster compounds, Coordination chemistry, Gallium, Hydrogenolysis, Ruthenium",

author = "Thomas Cadenbach and Christian Gemel and Rochus Schmid and Markus Halbherr and Kirill Yusenko and Mirza Cokoja and Fischer, {Roland A.}",

year = "2009",

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day = "11",

doi = "10.1002/anie.200805605",

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journal = "Angewandte Chemie - International Edition",

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Substituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru₂(Ga)(GaCp*) ₇(H)₃]. / Cadenbach, Thomas; Gemel, Christian; Schmid, Rochus et al.
En: Angewandte Chemie - International Edition, Vol. 48, N.º 21, 11.05.2009, p. 3872-3876.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Substituent-free gallium by hydrogenolysis of coordinated gaCp*

T2 - Synthesis and structure of highly fluxional [Ru2(Ga)(GaCp*) 7(H)3]

AU - Cadenbach, Thomas

AU - Gemel, Christian

AU - Schmid, Rochus

AU - Halbherr, Markus

AU - Yusenko, Kirill

AU - Cokoja, Mirza

AU - Fischer, Roland A.

PY - 2009/5/11

Y1 - 2009/5/11

N2 - All change: Complete ligand exchange through the hydrogenation of [Ru(η4-cod)(η6-cot)] in the presence of GaCp* under mild conditions leads to the title complex featuring a "naked" gallium atom bridging two ruthenium centers (see structure: C white, Ga blue, Ru red). This cluster can be considered as a trapped intermediate on the way to mixed-metal nanoparticles; cot=1,3,5- cyclooctatriene; cod=1,5-cyclooctadiene, Cp*=C5Me5.

AB - All change: Complete ligand exchange through the hydrogenation of [Ru(η4-cod)(η6-cot)] in the presence of GaCp* under mild conditions leads to the title complex featuring a "naked" gallium atom bridging two ruthenium centers (see structure: C white, Ga blue, Ru red). This cluster can be considered as a trapped intermediate on the way to mixed-metal nanoparticles; cot=1,3,5- cyclooctatriene; cod=1,5-cyclooctadiene, Cp*=C5Me5.

KW - Cluster compounds

KW - Coordination chemistry

KW - Gallium

KW - Hydrogenolysis

KW - Ruthenium

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U2 - 10.1002/anie.200805605

DO - 10.1002/anie.200805605

M3 - Artículo

AN - SCOPUS:70349973188

SN - 1433-7851

VL - 48

SP - 3872

EP - 3876

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21