Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex Cp*Ir(μ-C6H4N-NC6H4)IrCp*

Cesar H. Zambrano; Paul R. Sharp; Charles L. Barnes

doi:10.1021/om00008a001

Synthesis, Structure, and Reactivity of the Iridium Hydrazido-Bridged Complex CpIr(μ-C₆H₄N-NC₆H₄)IrCp

Cesar H. Zambrano, Paul R. Sharp, Charles L. Barnes

University of Missouri

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

14 Citas (Scopus)

Resumen

The hydrazido-bridged iridium complex (1; Cp* = C₅Me₅) reacts with H₂under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl₃Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br₂.

Idioma original	Inglés
Páginas (desde-hasta)	3607-3610
Número de páginas	4
Publicación	Organometallics
Volumen	14
N.º	8
DOI	https://doi.org/10.1021/om00008a001
Estado	Publicada - ago. 1995
Publicado de forma externa	Sí

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10.1021/om00008a001

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abstract = "The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.",

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AU - Sharp, Paul R.

AU - Barnes, Charles L.

PY - 1995/8

Y1 - 1995/8

N2 - The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.

AB - The hydrazido-bridged iridium complex (1; Cp* = C5Me5) reacts with H2under pressure with oxidation of the N—N bond to give (3) in its cis and trans forms. In the absence of hydrogen, 3 is converted back to 1 with reduction of the N=N bond. Complex 3 reacts with CCl3Br to give only the cis isomer of (4). Complex 4 is also prepared by reaction of 1 with HBr or Br2.

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DO - 10.1021/om00008a001

M3 - Artículo

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