The [Ga2(C5Me5)]+ ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga +

Beatrice Buchin; Christian Gemel; Thomas Cadenbach; Rochus Schmid; Roland A. Fischer

doi:10.1002/anie.200503028

The [Ga₂(C₅Me₅)]⁺ ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga ⁺

Beatrice Buchin, Christian Gemel, Thomas Cadenbach, Rochus Schmid, Roland A. Fischer

Ruhr-Universität Bochum

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

57 Citas (Scopus)

Resumen

(Figure Presented) Partial protolysis of GaCp* with [H-(OEt ₂)₂]⁺[BAr^F]^- afforded the Ga^I compound [Ga₂Cp*]⁺[BAr ^F]^- (see structure). Experimental and computational studies confirm the mainly ionic structure of the cation, in which the Ga ⁺ ions are only weakly covalently stabilized by a bridging Cp* ligand. Initial experiments point to the interesting synthetic potential of this compound as a source for Ga⁺ in solution.

Idioma original	Inglés
Páginas (desde-hasta)	1074-1076
Número de páginas	3
Publicación	Angewandte Chemie - International Edition
Volumen	45
N.º	7
DOI	https://doi.org/10.1002/anie.200503028
Estado	Publicada - 6 feb. 2006
Publicado de forma externa	Sí

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abstract = "(Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Ga2Cp*]+[BAr F]- (see structure). Experimental and computational studies confirm the mainly ionic structure of the cation, in which the Ga + ions are only weakly covalently stabilized by a bridging Cp* ligand. Initial experiments point to the interesting synthetic potential of this compound as a source for Ga+ in solution.",

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T2 - Bipyramidal double-cone structure and weakly coordinated, monovalent Ga +

AU - Buchin, Beatrice

AU - Gemel, Christian

AU - Cadenbach, Thomas

AU - Schmid, Rochus

AU - Fischer, Roland A.

PY - 2006/2/6

Y1 - 2006/2/6

N2 - (Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Ga2Cp*]+[BAr F]- (see structure). Experimental and computational studies confirm the mainly ionic structure of the cation, in which the Ga + ions are only weakly covalently stabilized by a bridging Cp* ligand. Initial experiments point to the interesting synthetic potential of this compound as a source for Ga+ in solution.

AB - (Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Ga2Cp*]+[BAr F]- (see structure). Experimental and computational studies confirm the mainly ionic structure of the cation, in which the Ga + ions are only weakly covalently stabilized by a bridging Cp* ligand. Initial experiments point to the interesting synthetic potential of this compound as a source for Ga+ in solution.

KW - Carbenoids

KW - Cyclopentadienyl compounds

KW - Gallium

KW - Group 13 elements

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