The [Ga2(C5Me5)]+ ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga +

Beatrice Buchin, Christian Gemel, Thomas Cadenbach, Rochus Schmid, Roland A. Fischer

Producción científica: Contribución a una revistaArtículorevisión exhaustiva

55 Citas (Scopus)

Resumen

(Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Ga2Cp*]+[BAr F]- (see structure). Experimental and computational studies confirm the mainly ionic structure of the cation, in which the Ga + ions are only weakly covalently stabilized by a bridging Cp* ligand. Initial experiments point to the interesting synthetic potential of this compound as a source for Ga+ in solution.

Idioma originalInglés
Páginas (desde-hasta)1074-1076
Número de páginas3
PublicaciónAngewandte Chemie - International Edition
Volumen45
N.º7
DOI
EstadoPublicada - 6 feb. 2006
Publicado de forma externa

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