The reaction of RhCp*(CH3)2(L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon-carbon bond activation reaction

Thomas Cadenbach; Christian Gemel; Rochus Schmid; Stefan Block; Roland A. Fischer

doi:10.1039/b410077h

The reaction of RhCp(CH₃)₂(L) (L = pyridine, dmso) with GaCp and AlCp*: A new type of carbon-carbon bond activation reaction

Thomas Cadenbach
, Christian Gemel
, Rochus Schmid
, Stefan Block
, Roland A. Fischer^*

^*Autor correspondiente de este trabajo

Ruhr-Universität Bochum

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

20 Citas (Scopus)

Resumen

Reaction of RhCp*(L)(CH₃)₂ (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe₄GaMe₃)]. [Cp*Rh(CH₃)₂(GaCp*)] could be isolated and identified as an intermediate in this reaction.

Idioma original	Inglés
Páginas (desde-hasta)	3171-3172
Número de páginas	2
Publicación	Dalton Transactions
N.º	20
DOI	https://doi.org/10.1039/b410077h
Estado	Publicada - 21 oct. 2004
Publicado de forma externa	Sí

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10.1039/b410077h

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abstract = "Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.",

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T2 - A new type of carbon-carbon bond activation reaction

AU - Cadenbach, Thomas

AU - Gemel, Christian

AU - Schmid, Rochus

AU - Block, Stefan

AU - Fischer, Roland A.

PY - 2004/10/21

Y1 - 2004/10/21

N2 - Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

AB - Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

UR - https://www.scopus.com/pages/publications/9244250324

U2 - 10.1039/b410077h

DO - 10.1039/b410077h

M3 - Artículo

AN - SCOPUS:9244250324

SN - 1477-9226

SP - 3171

EP - 3172

JO - Dalton Transactions

JF - Dalton Transactions

IS - 20