Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst; Thomas Cadenbach; Daniel Betz; Colin Finn; Jason B. Love

doi:10.1039/c4dt03592e

Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst, Thomas Cadenbach, Daniel Betz, Colin Finn, Jason B. Love

EaStCHEM School of Chemistry, University of Edinburgh

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

25 Citas (Scopus)

Resumen

Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

Idioma original	Inglés
Páginas (desde-hasta)	2066-2070
Número de páginas	5
Publicación	Dalton Transactions
Volumen	44
N.º	5
DOI	https://doi.org/10.1039/c4dt03592e
Estado	Publicada - 7 feb. 2015
Publicado de forma externa	Sí

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abstract = "Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.",

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AU - Cadenbach, Thomas

AU - Betz, Daniel

AU - Finn, Colin

AU - Love, Jason B.

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N2 - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

AB - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

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U2 - 10.1039/c4dt03592e

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Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

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