Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst; Thomas Cadenbach; Daniel Betz; Colin Finn; Jason B. Love

doi:10.1039/c4dt03592e

Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

James R. Pankhurst
, Thomas Cadenbach
, Daniel Betz
, Colin Finn
, Jason B. Love^*

^*Autor correspondiente de este trabajo

EaStCHEM School of Chemistry, University of Edinburgh

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

27 Citas (Scopus)

Resumen

Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

Idioma original	Inglés
Páginas (desde-hasta)	2066-2070
Número de páginas	5
Publicación	Dalton Transactions
Volumen	44
N.º	5
DOI	https://doi.org/10.1039/c4dt03592e
Estado	Publicada - 7 feb. 2015
Publicado de forma externa	Sí

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title = "Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes",

abstract = "Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.",

author = "Pankhurst, \{James R.\} and Thomas Cadenbach and Daniel Betz and Colin Finn and Love, \{Jason B.\}",

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T2 - Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

AU - Pankhurst, James R.

AU - Cadenbach, Thomas

AU - Betz, Daniel

AU - Finn, Colin

AU - Love, Jason B.

PY - 2015/2/7

Y1 - 2015/2/7

N2 - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

AB - Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

UR - https://www.scopus.com/pages/publications/84921517030

U2 - 10.1039/c4dt03592e

DO - 10.1039/c4dt03592e

M3 - Artículo

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VL - 44

SP - 2066

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JO - Dalton Transactions

JF - Dalton Transactions

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Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

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